Hi,
I would suggest you watch all the tutorials you can and sceencast, it will start to make sense. Your issue here as well, is that you are learning Unity too isn't it? so you have twice the amount of information to learn. For example to properly set up physics object to fire trigger events, one of them must have a physics component, else it will not work. It's full of little things like that, that you will learn as you go and experiment.
Even if you don't know how to script, I suggest you properly refer to the Unity Help documentation and abosrb as much as a you can ( at least to know where to find back the info a particualr feature). I personally always have the unity help open on my browser. I can't do without it...
bye,
Jean